POLYANILINE DISPERSIONS .4. POLYMERIZATION SEEDED BY POLYANILINE PARTICLES

被引：38

作者：

STEJSKAL, J

SPIRKOVA, M

KRATOCHVIL, P

机构：

[1] Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague

来源：

ACTA POLYMERICA | 1994年 / 45卷 / 05期

关键词：

D O I：

10.1002/actp.1994.010450509

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Aniline hydrochloride was polymerized in water and in 1 M hydrochloric acid by oxidation with ammonium persulfate. The macroscopic precipitation of polyaniline was prevented by the presence of poly(vinyl alcohol). The changes of pH occurring during the reaction were recorded. Their relation to color transitions is discussed. The reaction was accelerated by introduction of seed polyaniline particles. The properties of resulting dispersions were not affected by seeding. The particle diameter was about 310 nm for polymerization in water and about 420 nm in 1 M hydrochloric acid.

引用

收藏

页码：385 / 388

页数：4

相关论文

共 34 条

[11] STABLE AQUEOUS DISPERSIONS OF POLYANILINE [J].

GOSPODINOVA, N ;

MOKREVA, P ;

TERLEMEZYAN, L .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (13) :923-924

[12] SEEDED POLYMERIZATION OF VINYL-ACETATE USING MONODISPERSE POLYVINYL ACETATE) LATEX-PARTICLES [J].

HAYASHI, S ;

KOMATSU, A ;

HIRAI, T .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1989, 27 (01) :157-169

[13] OPTICAL-PROPERTIES OF POLYANILINE [J].

HUANG, WS ;

MACDIARMID, AG .

POLYMER, 1993, 34 (09) :1833-1845

[14] POLYANILINE, A NOVEL CONDUCTING POLYMER - MORPHOLOGY AND CHEMISTRY OF ITS OXIDATION AND REDUCTION IN AQUEOUS-ELECTROLYTES [J].

HUANG, WS ;

HUMPHREY, BD ;

MACDIARMID, AG .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 :2385-&

[15] POLYANILINE WITH HIGH INTRINSIC OXIDATION-STATE [J].

KANG, ET ;

NEOH, KG ;

TAN, KL .

SURFACE AND INTERFACE ANALYSIS, 1993, 20 (10) :833-840

[16]

Khan A., 1985, MAKROMOL CHEM, V10, P215

[17]

KRIVOSHEI IV, 1991, POLYACETYLENE POLYAR, P119

[18] DISPERSION POLYMERIZATION OF STYRENE IN ETHANOL - MONOMER PARTITIONING BEHAVIOR AND LOCUS OF POLYMERIZATION [J].

LU, YY ;

ELAASSER, MS ;

VANDERHOFF, JW .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1988, 26 (06) :1187-1203

[19] POLYANILINE - SYNTHESIS AND PROPERTIES OF PERNIGRANILINE BASE [J].

MACDIARMID, AG ;

MANOHAR, SK ;

MASTERS, JG ;

SUN, Y ;

WEISS, H ;

EPSTEIN, AJ .

SYNTHETIC METALS, 1991, 41 (1-2) :621-626

[20] POLYANILINE - ALLOWED OXIDATION-STATES [J].

MASTERS, JG ;

SUN, Y ;

MACDIARMID, AG ;

EPSTEIN, AJ .

SYNTHETIC METALS, 1991, 41 (1-2) :715-718

← 1 2 3 4 →