SELECTIVE SYNTHESES OF CYCLOBUTANE-BETA-AMINOCARBOXYLIC ACID-DERIVATIVES BY THE RUTHENIUM COMPLEX-CATALYZED REACTION OF ALLYLAMINES WITH ACRYLIC COMPOUNDS

被引：34

作者：

MITSUDO, T

ZHANG, SW

SATAKE, N

KONDO, T

WATANABE, Y

机构：

[1] Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University, Sakyo-ku, Kyoto

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 38期

关键词：

RUTHENIUM CATALYST; ALLYLAMINE; ACRYLATE; CYCLOADDUCT;

D O I：

10.1016/S0040-4039(00)61138-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allylamines react with acrylic compounds in the presence of Ru(cod)(cot) catalyst to give cyclobutane-beta-amino acid derivatives in high yield (up to 85%); cod = cycloocta-1,5-diene, cot = cycloocta-1,3,5-triene.

引用

页码：5533 / 5536

页数：4

共 5 条

[1] ENAMINE CHEMISTRY .4. CYCLOADDITION REACTIONS OF ENAMINES DERIVED FROM ALDEHYDES + ACYCLIC KETONES [J].

BRANNOCK, KC ;

KELLY, CA ;

BURPITT, RD ;

BELL, A .

JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (04) :801-&

[2] RUTHENIUM COMPLEX-CATALYZED HIGHLY SELECTIVE CODIMERIZATION OF ACETYLENES AND ALKENES [J].

MITSUDO, T ;

ZHANG, SW ;

NAGAO, M ;

WATANABE, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (08) :598-599

[3] RUTHENIUM COMPLEX-CATALYZED SELECTIVE SYNTHESES OF 3,5-DIENOIC ACID-DERIVATIVES BY COUPLING OF 1,3-DIENES OR ALLYLIC CARBONATES WITH ACRYLIC COMPOUNDS [J].

MITSUDO, T ;

ZHANG, SW ;

KONDO, T ;

WATANABE, Y .

TETRAHEDRON LETTERS, 1992, 33 (03) :341-344

[4] A NEW SYNTHESIS OF 2-ALKYL AND 2-ACYL KETONES [J].

STORK, G ;

TERRELL, R ;

SZMUSZKOVICZ, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (07) :2029-2030

[5] ENAMINE ALKYLATION AND ACYLATION OF CARBONYL COMPOUNDS [J].

STORK, G ;

SZMUSZKOVICZ, J ;

TERRELL, R ;

BRIZZOLARA, A ;

LANDESMAN, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (02) :207-&

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