HYDROGEN EVOLUTION REACTION - A KINETIC-STUDY ON ELECTRODES WITH 2 DOMAINS OF ADSORPTION SITES

被引：12

作者：

DECHIALVO, MRG

CHIALVO, AC

机构：

[1] Programa de Electroquímica Aplicada e Ingeniería Electroquímica (PRELINE), Facultad de Ingeniería Química (UNL), 3000 Santa Fe

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1995年 / 388卷 / 1-2期

关键词：

HYDROGEN EVOLUTION REACTION; HETEROGENEOUS ELECTRODES;

D O I：

10.1016/0022-0728(94)03849-X

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The present work deals with a theoretical study of the hydrogen evolution reaction (HER) on heterogeneous electrode surfaces characterized by two domains of adsorption energies for the reaction intermediate, which were simulated through a normal bimodal distribution function. The HER was described by the Volmer-Heyrovsky-Tafel mechanism, which was solved without kinetic approximations and in steady state conditions. The dependences of the current density and the surface coverage on the overpotential were evaluated as well as the adsorption isotherm. On the basis of this simulation, it has been concluded that the surface heterogeneity produces substantial modifications of the kinetic behaviour of the Volmer-Heyrovsky-Tafel mechanism.

引用

页码：215 / 224

页数：10

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