MULTIPLE BONDING BETWEEN GERMANIUM AND THE CHALCOGENS - THE SYNTHESES AND STRUCTURES OF THE TERMINAL CHALOGENIDO COMPLEXES (ETA(4)-ME(8)TAA)GEE (E=S,SE,TE)

被引：83

作者：

KUCHTA, MC ^{[1
]}

PARKIN, G ^{[1
]}

机构：

[1] COLUMBIA UNIV, DEPT CHEM, NEW YORK, NY 10027 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 11期

关键词：

D O I：

10.1039/c39940001351

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of terminal chalcogenido complexes of germanium supported by ligation of the macrocyclic octamethyldibenzotetraaza[14]annulene dianion (eta(4)-Me(8)taa)GeE (E = S, Se, Te) has been prepared by addition of the chalcogen to (eta(4)-Me(8)taa)Ge; structural studies on these complexes indicate that the bonding of the Ge approximate to E moiety is best described as intermediate between the Ge-E and Ge=E resonance structures.

引用

页码：1351 / 1352

页数：2

共 36 条

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