POLYMERIC ORGANOSILICON SYSTEMS .24. ANIONIC-POLYMERIZATION OF 4,5,10-TRISILABICYCLO[6.3.0]UNDECA-1(11),8-DIENE-2,6-DIYNES

被引：27

作者：

TOYODA, E

KUNAI, A

ISHIKAWA, M

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Hiroshima University

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 03期

关键词：

D O I：

10.1021/om00003a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Anionic ring-opening polymerization of cyclic silole derivatives has been reported. The reaction of 4,5,10-trisilabicyclo[6.3.0]undeca-1(11),8-diene-2,6-diynes with a catalytic amount of tetrabutylammonium fluoride afforded polymers that have a regular alternating arrangement of a disilanylene unit and 3,4-diethynylene-substituted silole system.

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页码：1089 / 1091

页数：3

相关论文

共 20 条

[1] NEW POLY[(SILYLENE)DIACETYLENES] AND POLY[(GERMYLENE)DIACETYLENES] - SYNTHESIS AND CONDUCTIVE PROPERTIES [J].

BREFORT, JL ;

CORRIU, RJP ;

GERBIER, P ;

GUERIN, C ;

HENNER, BJL ;

JEAN, A ;

KUHLMANN, T ;

GARNIER, F ;

YASSAR, A .

ORGANOMETALLICS, 1992, 11 (07) :2500-2506

[2] PREPARATION OF OLIGOMERS CONTAINING TETRAPHENYLSILOLE, ACETYLENE AND AROMATIC-GROUPS IN THE MAIN-CHAIN, AND INCORPORATION OF IRON CARBONYL [J].

CORRIU, RJP ;

DOUGLAS, WE ;

YANG, ZX .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 456 (01) :35-39

[3]

FUKUSHIMA M, 1994, 2ND S SIL BAS POL TO, P183

[4]

HONG HH, 1989, POLYM BULL, V22, P363

[5]

HU SS, 1989, POLYM BULL, V21, P133

[6] POLYMERIC ORGANOSILICON SYSTEMS .17. SYNTHESIS AND PHOTOCHEMICAL AND CONDUCTING PROPERTIES OF POLY[O-(DISILADYLENE)PHENYLENE AND M-(DISILANYLENE)PHENYLENE]S [J].

ISHIKAWA, M ;

SAKAMOTO, H ;

ISHII, M ;

OHSHITA, J .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (13) :3281-3289

[7] POLYMERIC ORGANOSILICON SYSTEMS .12. SYNTHESIS AND ANIONIC RING-OPENING POLYMERIZATION OF 1,2,5,6-TETRASILACYCLOOCTA-3,7-DIYNES [J].

ISHIKAWA, M ;

HATANO, T ;

HASEGAWA, Y ;

HORIO, T ;

KUNAI, A ;

MIYAI, A ;

ISHIDA, T ;

TSUKIHARA, T ;

YAMANAKA, T ;

KOIKE, T ;

SHIOYA, J .

ORGANOMETALLICS, 1992, 11 (04) :1604-1618

[8] POLYMERIC ORGANOSILICON SYSTEM .8. SYNTHESIS OF POLY[(DISILANYLENE)DIETHYNYLENE] WITH HIGHLY CONDUCTING PROPERTIES [J].

ISHIKAWA, M ;

HASEGAWA, Y ;

KUNAI, A ;

YAMANAKA, T .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 381 (03) :C57-C59

[9] POLYMERIC ORGANOSILICON SYSTEMS .15. THERMAL AND RADICAL-INDUCED POLYMERIZATION OF 1,2,5,6-TETRASILACYCLOOCTA-3,7-DIYNES [J].

ISHIKAWA, M ;

HORIO, T ;

HATANO, T ;

KUNAI, A .

ORGANOMETALLICS, 1993, 12 (06) :2078-2084

[10]

ISHIKAWA M, 1988, ACS SYM SER, V360, pCH16