ENANTIOSELECTIVE TRANSESTERIFICATION OF 2-METHYL-1,3-PROPANEDIOL DERIVATIVES CATALYZED BY PSEUDOMONAS-FLUORESCENS LIPASE IN AN ORGANIC-SOLVENT

被引：34

作者：

GRISENTI, P ^{[1
]}

FERRABOSCHI, P ^{[1
]}

MANZOCCHI, A ^{[1
]}

SANTANIELLO, E ^{[1
]}

机构：

[1] UNIV MILANO,DIPARTIMENTO CHIM & BIOCHIM MED,VIA SALDINI 50,I-20133 MILAN,ITALY

来源：

TETRAHEDRON | 1992年 / 48卷 / 18期

关键词：

D O I：

10.1016/S0040-4020(01)92273-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The irreversible transesterification of racemic 2-methyl-1,3-propanediol derivatives, the monoethers 3a, 3b, 5a, and the monobenzoate 5b, with vinyl acetate catalyzed by Pseudomonas fluorescens lipase in chloroform affords enantiomerically pure chiral synthons.

引用

页码：3827 / 3834

页数：8

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