THE ELECTROOXIDATION OF CO - A TEST REACTION IN ELECTROCATALYSIS

被引：183

作者：

BEDEN, B ^{[1
]}

LAMY, C ^{[1
]}

DETACCONI, NR ^{[1
]}

ARVIA, AJ ^{[1
]}

机构：

[1] NATL UNIV LA PLATA,FAC CIENCIAS EXACTAS,INST INVEST FISICOQUIM TEOR & APLICADAS,RA-1900 LA PLATA,ARGENTINA

来源：

ELECTROCHIMICA ACTA | 1990年 / 35卷 / 04期

关键词：

D O I：

10.1016/0013-4686(90)90002-H

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

This review paper aims to show how the electrochemical behaviour of CO plays a key role in the understanding of the reaction mechanism of many electrocatalytic oxidations of small organic molecules. For that purpose, the adsorption of CO on noble metal electrodes, eventually modified by foreign metal adatoms, is reviewed, taking into account both experimental (electrochemical and spectroscopic techniques) and theoretical (Extended Hückel Model) approaches. Data from the gas phase-solid metal interface are also considered. © 1990.

引用

页码：691 / 704

页数：14

共 130 条

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BEWICK A, 1981, 32ND M INT SOC EL DU, P92

[32] A NEW MODEL FOR CO ORDERING AT HIGH COVERAGES ON LOW INDEX METAL-SURFACES - A CORRELATION BETWEEN LEED, HREELS AND IRS .2. CO ADSORBED ON FCC(111) AND HCP(0001) SURFACES [J].