LINEAR 2,2-DIARYL-SUBSTITUTED TRISILANES - STRUCTURE AND PHOTOLYSIS TO DISILENES

被引：9

作者：

ARCHIBALD, RS ^{[1
]}

VANDENWINKEL, Y ^{[1
]}

POWELL, DR ^{[1
]}

WEST, R ^{[1
]}

机构：

[1] UNIV WISCONSIN,DEPT CHEM,MADISON,WI 53706

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 446卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-328X(93)80035-A

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis of the new disilene, E/Z-IsMesSi=SiIsMes (1) is reported; the isomer Is2Si=SiMes2 (2) was obtained by photolysis of a mixture of Mes2Si(SiMe3)2 (3) and Is2Si(SiMe3)2 (5). Isomerization of 1 half arrow right over half arrow left 2 does not take place up to 80-degrees-C. X-Ray crystal structures are reported for trisilanes 3, IsMesSi(SiMe3)2 (4), and 5.

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页码：67 / 72

页数：6

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