HIGH-YIELDING CATALYTIC SYNTHESIS OF GLYCOSYL AZIDES FROM PERACYLATED SUGARS

被引：23

作者：

MATSUBARA, K

MUKAIYAMA, T

机构：

来源：

CHEMISTRY LETTERS | 1994年 / 02期

关键词：

D O I：

10.1246/cl.1994.247

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a catalyst generated from SnCl4 and AgClO4, or Yb(OTf)(3), various glycosyl azides are synthesized in high yields with complete stereoselectivities from peracylated sugars and trimethylsilyl azide by choosing a suitable solvent such as dichloromethane or nitromethane.

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页码：247 / 250

页数：4

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