ASYMMETRIC HYDROFORMYLATIONS OF SULFUR-CONTAINING OLEFINS CATALYZED BY BINAPHOS-RH(I) COMPLEXES

被引：48

作者：

NANNO, T ^{[1
]}

SAKAI, N ^{[1
]}

NOZAKI, K ^{[1
]}

TAKAYA, K ^{[1
]}

机构：

[1] KYOTO UNIV,GRAD SCH ENGN,DEPT CHEM MAT,SAKYO KU,KYOTO 60601,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 10期

关键词：

D O I：

10.1016/0957-4166(95)00339-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Asymmetric hydroformylations of vinyl sulfides, allyl sulfides, and allyl sulfones catalyzed by (R,S)-BINAPHOS/Rh(acac)(CO)(2) afforded the corresponding branched oxo aldehydes as major products in 60-89% ee. Use of bulkier substituents on the sulfur in vinyl sulfides gave the branched oxo-aldehydes in higher regio- and enantioselectivities.

引用

页码：2583 / 2591

页数：9

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