PHYSICAL-PROPERTIES OF POLYPYRROLE FILMS CONTAINING TETRACYANONICKELATE(II) ANIONS, PPY-NI(CN)4

被引：14

作者：

CERVINI, R

FLEMING, RJ

MURRAY, KS

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

[2] MONASH UNIV,DEPT PHYS,CLAYTON,VIC 3168,AUSTRALIA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1992年 / 2卷 / 11期

关键词：

CONDUCTING POLYMER; POLYPYRROLE; TETRACYANONICKELATE ANION; CONDUCTIVITY; ENVIRONMENTAL STABILITY;

D O I：

10.1039/jm9920201115

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Polypyrrole-tetracyanonickelate, PPy-Ni(CN)4, has been synthesized in thin-film form by electrochemical oxidation of pyrrole in aqueous or non-aqueous media. The room-temperature electrical conductivity of one of the films (122 S cm-1) is the highest reported to date for any PPy-metal anion system. The temperature dependence of the conductivity is consistent with the Mott variable-range hopping model. Some of the films show good stability in air at room temperature, their conductivity decreasing by less than 7% over 50 days.

引用

页码：1115 / 1121

页数：7

共 48 条

[41]

Skotheim T., 1986, HDB CONDUCTING POLYM, V1

[42] ELECTROCHEMICAL DOPING OF POLYTHIOPHENE IN AQUEOUS-MEDIUM - ELECTRICAL-PROPERTIES AND STABILITY [J].