PYRROLYL-N AND PYRROLYL-C COMPLEXES OF THE CHIRAL RHENIUM FRAGMENT [(ETA(5)-C5H5)RE(NO)(PPH3)]+ - SYNTHESIS, PROTONATION, AND REARRANGEMENT CHEMISTRY

被引：29

作者：

JOHNSON, TJ ^{[1
]}

ARIF, AM ^{[1
]}

GLADYSZ, JA ^{[1
]}

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 12期

关键词：

D O I：

10.1021/om00036a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pyrrolyl-N complex (eta5-C5H5)Re(NO)-(PPh3)(NC4H4) and TfOH or HBF4.OEt2 react to give 2H-pyrrole complexes [(eta5-C5H5)Re(NO)(PPh3)-(N=CHCH=CHCH2)]+X-. These rearrange to the carbon-ligated species [(eta5-C5H5)Re(NO)(PPh3)-(C=NHCH2CH=CH)]+X-, which is characterized crystallographically and treated with KH to give the pyrrolyl-C complex (eta5-C5H5)Re(NO)(PPh3)(C=CH-CH=CHNH).

引用

页码：4728 / 4730

页数：3

共 23 条

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