HYDROSILYLATION OF ENONES - PLATINUM DIVINYLTETRAMETHYLDISILOXANE COMPLEX IN PREPARATION OF TRIISOPROPYLSILYL AND TRIPHENYLSILYL ENOL ETHERS

被引：44

作者：

JOHNSON, CR

RAHEJA, RK

机构：

[1] Department of Chemistry, Wayne State University, Detroit

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 09期

关键词：

D O I：

10.1021/jo00088a006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enones are regioselectively converted to triisopropylsilyl and triphenylsilyl enol ethers in high yields using triisopropylsilane or triphenylsilane and platinum divinyltetramethyldisiloxane complex 1 (Karstedt's catalyst).

引用

页码：2287 / 2288

页数：2

共 12 条

[1] HYDROSILYLATION OF ALPHA,BETA-UNSATURATED ALDEHYDES AND KETONES BY TRANS-DI-MU-HYDRIDO-BIS(SILYL)BIS-(TRIALKYLPHOSPHINE)DIPLATINUM COMPLEXES [J].

BARLOW, AP ;

BOAG, NM ;

STONE, FGA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 191 (01) :39-47

[2] REACTION OF TRIETHYLSILANE WITH ALPHA-ETHYLENIC ALDEHYDES IN PRESENCE OF NICKEL OR PALLADIUM CATALYSTS [J].

BOURHIS, R ;

FRAINNET, E ;

MOULINES, F .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 141 (02) :157-171

[3]

BROWNBRIDGE P, 1983, SYNTHESIS-STUTTGART, P85

[4] HYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RHODIUM(I) AS AN EFFECTIVE CATALYST FOR THE REGIOSPECIFIC HYDROSILATION OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS [J].

CHAN, TH ;

ZHENG, GZ .

TETRAHEDRON LETTERS, 1993, 34 (19) :3095-3098

[5]

Colvin E. W., 1981, SILICON ORGANIC SYNT

[6]

LEWIS LN, 1992, ADV CHEM SER, V230, P541

[7] NEW TRIALKYLSILYL ENOL ETHER CHEMISTRY - REGIOSPECIFIC AND STEREOSPECIFIC SEQUENTIAL ELECTROPHILIC ADDITION [J].

MAGNUS, P ;

MUGRAGE, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (01) :462-464

[8] NEW TRIALKYLSILYL ENOL ETHER CHEMISTRY - DIRECT BETA-AZIDO FUNCTIONALIZATION OF TRIISOPROPYLSILYL ENOL ETHERS [J].

MAGNUS, P ;

LACOUR, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (02) :767-769

[9] RH4(CO)12, CO2RH2(CO)12, AND CO3RH(CO)12 AS EFFECTIVE CATALYSTS FOR HYDROSILYLATION OF ISOPRENE, CYCLOHEXANONE, AND CYCLOHEXENONE [J].

OJIMA, I ;

DONOVAN, RJ ;

CLOS, N .

ORGANOMETALLICS, 1991, 10 (08) :2606-2610

[10] REDUCTION OF CARBONYL-COMPOUNDS VIA HYDROSILYLATION .4. HIGHLY REGIOSELECTIVE REDUCTIONS OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS [J].

OJIMA, I ;

KOGURE, T .

ORGANOMETALLICS, 1982, 1 (10) :1390-1399

← 1 2 →