TRANSITION-METAL-CATALYZED RING-OPENING POLYMERIZATION OF SILICON-BRIDGED [1]FERROCENOPHANES AT AMBIENT-TEMPERATURE

被引：114

作者：

NI, YZ

RULKENS, R

PUDELSKI, JK

MANNERS, I

机构：

[1] Department of Chemistry, University of Toronto, Toronto, Ontario, M5S 1A1

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1995年 / 16卷 / 09期

关键词：

D O I：

10.1002/marc.1995.030160901

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new route to poly(ferrocenylsilanes) under mild conditions via the ring-opening polymerization of silicon-bridged [1]ferrocenophanes is presented. Catalytic amounts of the transition metal complexes [Rh(cyclooctene)(2)(mu-Cl)](2), Pd(1,5-cycloocladiene)Cl-2, PdCl2 and PtCl2 in C6D6 at room temperature afforded high molecular weight poly(ferrocenylsilanes) (2). In some cases a symmetrical dimer (3) was obtained as a byproduct.

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页码：637 / 641

页数：5

相关论文

共 19 条

[1] INORGANIC-ORGANIC POLYMERS [J].

ALLCOCK, HR .

ADVANCED MATERIALS, 1994, 6 (02) :106-115

[2]

ALLCOCK HR, 1994, ACS S SER, V572

[3]

BAYER R, 1993, MAKROMOL CHEM-RAPID, V14, P359

[4] POLYFERROCENYLENE PERSULFIDES [J].

BRANDT, PF ;

RAUCHFUSS, TB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (05) :1926-1927

[5] ROLE OF TRANSITION-METAL IN HOMOGENEOUS CATALYTIC POLYMERIZATION OF STRAINED ORGANOSILICON HETEROCYCLES [J].

CUNDY, CS ;

EABORN, C ;

LAPPERT, MF .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 44 (02) :291-&

[6]

FOUCHER DA, 1993, MAKROMOL CHEM-RAPID, V14, P63

[7] RING-OPENING POLYMERIZATION OF STRAINED, RING-TILTED FERROCENOPHANES - A ROUTE TO HIGH-MOLECULAR-WEIGHT POLY(FERROCENYLSILANES) [J].

FOUCHER, DA ;

TANG, BZ ;

MANNERS, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (15) :6246-6248

[8] FERROCENE-CONTAINING POLYAMIDES AND POLYUREAS [J].

GONSALVES, K ;

LIN, ZR ;

RAUSCH, MD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (13) :3862-3863

[9] Ring-opening polymerization of metallocenophanes: A new route to transition metal-based polymers [J].

Manners, I .

ADVANCES IN ORGANOMETALLIC CHEMISTRY, VOL 37, 1995, 37 :131-168

[10] RING-OPENING POLYMERIZATION OF METALLOCENOPHANES [J].

MANNERS, I .

ADVANCED MATERIALS, 1994, 6 (01) :68-71