SYNTHESIS OF BETA-HYDROXY NITRILES VIA INDIUM-INDUCED COUPLING OF BROMOACETONITRILE WITH CARBONYL-COMPOUNDS

被引:22
作者
ARAKI, S [1 ]
YAMADA, M [1 ]
BUTSUGAN, Y [1 ]
机构
[1] NAGOYA INST TECHNOL, DEPT APPL CHEM, GOKISO CHO, SHOWA KU, NAGOYA, AICHI 466, JAPAN
关键词
D O I
10.1246/bcsj.67.1126
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The organoindium reagent, derived from indium metal and bromoacetoiiitrile, reacted with carbonyl compounds in the presence of chlorotrimethylsilane to give, after hydrolysis, beta-hydroxy nitriles. The coupling proceeded with high chemoselectivity, though the diastereoselectivity was low.
引用
收藏
页码:1126 / 1129
页数:4
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