RATE CONSTANTS FOR THE ADDITIONS OF CYCLOHEXYL RADICALS TO ACRYLAMIDES, IMIDES AND SULFONIMIDES

被引：7

作者：

CURRAN, DP ^{[1
]}

QI, HY ^{[1
]}

PORTER, NA ^{[1
]}

SU, Q ^{[1
]}

WU, WX ^{[1
]}

机构：

[1] DUKE UNIV,DEPT CHEM,DURHAM,NC 27706

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 28期

关键词：

D O I：

10.1016/0040-4039(93)88066-R

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Competition experiments are used to provide estimated rate constants for the addition of cyclohexyl radical to a series of acrylamides, imides and sulfonimides.

引用

页码：4489 / 4492

页数：4

共 13 条

[1] ASYMMETRIC RADICAL-ADDITION, CYCLIZATION, AND ANNULATION REACTIONS WITH OPPOLZER CAMPHOR SULTAM [J].

CURRAN, DP ;

SHEN, W ;

ZHANG, JC ;

HEFFNER, TA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (18) :6738-6740

[2] 1,2-STEREOINDUCTION AND 1,4-STEREOINDUCTION IN REACTIONS OF CHIRAL RADICALS [J].

GIESE, B ;

ZEHNDER, M ;

ROTH, M ;

ZEITZ, HG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (18) :6741-6742

[3] COMPETITION METHODS AND SCALES FOR ALKYL RADICAL REACTION-KINETICS [J].

NEWCOMB, M .

TETRAHEDRON, 1993, 49 (06) :1151-1176

[4] COMPETITION RATE CONSTANTS FOR ADDITION OF CYCLOHEXYL RADICAL TO AMIDE SUBSTITUTED ALKENES - ORIGINS OF ACYCLIC STEREOSELECTION IN RADICAL ADDITIONS [J].

PORTER, NA ;

WU, WX ;

MCPHAIL, AT .

TETRAHEDRON LETTERS, 1991, 32 (06) :707-710

[5] ADDITION-REACTIONS OF AMIDE-SUBSTITUTED RADICALS - CONTROL OF STEREOCHEMISTRY IN ACRYLAMIDE FREE-RADICAL ADDITIONS [J].

PORTER, NA ;

SWANN, E ;

NALLY, J ;

MCPHAIL, AT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (18) :6740-6741

[6] RADICAL-ADDITION TO AMIDE-SUBSTITUTED ALKENES - STEREOSELECTIVE INTERMOLECULAR RADICAL ADDITIONS [J].

PORTER, NA ;

SCOTT, DM ;

LACHER, B ;

GIESE, B ;

ZEITZ, HG ;

LINDNER, HJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (21) :8311-8312

[7] ORIGINS OF STEREOSELECTIVITY IN RADICAL ADDITIONS - REACTIONS OF ALKENES AND RADICALS BEARING OXAZOLIDINE AND THIAZOLIDINE AMIDE GROUPS [J].

PORTER, NA ;

ROSENSTEIN, IJ ;

BREYER, RA ;

BRUHNKE, JD ;

WU, WX ;

MCPHAIL, AT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (20) :7664-7676

[8] ACYCLIC STEREOCHEMICAL CONTROL IN FREE-RADICAL REACTIONS [J].

PORTER, NA ;

GIESE, B ;

CURRAN, DP .

ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (10) :296-304

[9] STEREOSELECTIVE INTERMOLECULAR RADICAL ADDITIONS TO AMIDE-SUBSTITUTED ALKENES [J].

PORTER, NA ;

SCOTT, DM ;

ROSENSTEIN, IJ ;

GIESE, B ;

VEIT, A ;

ZEITZ, HG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (05) :1791-1799

[10] CONTROL OF STEREOCHEMISTRY IN FREE-RADICAL REACTIONS WITH OXAZOLIDINE AUXILIARIES [J].

PORTER, NA ;

BRUHNKE, JD ;

WU, WX ;

ROSENSTEIN, IJ ;

BREYER, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (20) :7788-7790

← 1 2 →