ELECTRONIC-SPECTRA OF JET-COOLED CATIONS OF HYDROGEN-BONDED COMPLEXES OF PHENOL

被引：25

作者：

SATO, S

EBATA, T

MIKAMI, N

机构：

[1] Department of Chemistry, Faculty of Science, Tohoku University, Aoba-ku, Sendai, 980, Aramaki

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1994年 / 50卷 / 8-9期

关键词：

D O I：

10.1016/0584-8539(94)E0051-B

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Electronic spectra of hydrogen-bonded complex cations of phenol with N(CH3)3, NH3 and H2O were investigated by photodissociation spectroscopy combined with a new method for the generation of jet-cooled molecular complex ions. The method involves the ionization of phenol followed by a jet expansion for the efficient formation of the complex ions as well as for the cooling. Well-resolved vibronic bands, including the bands due to intermolecular stretching vibrations, were obtained for the complex ions of phenol with N(CH3)3 and NH3. Differences between the ionic and neutral forms of these complexes were discussed on the basis of the results.

引用

收藏

页码：1413 / 1419

页数：7

相关论文

共 22 条

[11] MASS-SELECTED 2-COLOR MULTIPHOTON IONIZATION OF THE HYDROGEN-BONDED COMPLEX C6H5OH-N(CH3)3 - GENERATION OF THE PROTONATED ION HN(CH3)3+ [J].

MIKAMI, N ;

SUZUKI, I ;

OKABE, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (20) :5242-5247

[12] A NEW APPROACH TO VIBRATIONAL SPECTROSCOPY OF ION CLUSTERS - THE ZERO KINETIC-ENERGY (ZEKE) PHOTOELECTRON-SPECTRUM OF THE PHENOL WATER COMPLEX [J].

REISER, G ;

DOPFER, O ;

LINDNER, R ;

HENRI, G ;

MULLERDETHLEFS, K ;

SCHLAG, EW ;

COLSON, SD .

CHEMICAL PHYSICS LETTERS, 1991, 181 (01) :1-4

[13] RESONANCE-ENHANCED MULTIPHOTON DISSOCIATION SPECTROSCOPY OF THE FORBIDDEN B[-X TRANSITION OF THE GAS-PHASE CHLOROBENZENE CATION [J].

RIPOCHE, X ;

DIMICOLI, I ;

LECALVE, J ;

PIUZZI, F ;

BOTTER, R .

CHEMICAL PHYSICS, 1988, 124 (02) :305-313

[14]

SHUTZ M, 1993, J CHEM PHYS, V98, P3763

[15] CLUSTER ION DIP SPECTROSCOPY OF HYDROGEN-BONDED PHENOL(H2O)N CLUSTERS, N=0-4 [J].

STANLEY, RJ ;

CASTLEMAN, AW .

JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (12) :7744-7756

[16] PICOSECOND STUDIES OF PROTON-TRANSFER IN CLUSTERS .2. DYNAMICS AND ENERGETICS OF SOLVATED PHENOL CATION [J].

STEADMAN, J ;

SYAGE, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (18) :6786-6795

[17]

STEADMAN J, 1992, J PHYS CHEM-US, V96, P9606

[18] PICOSECOND MEASUREMENTS OF PHENOL EXCITED-STATE PROTON-TRANSFER IN CLUSTERS .1. SOLVENT BASICITY AND CLUSTER SIZE EFFECTS [J].

SYAGE, JA ;

STEADMAN, J .

JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (04) :2497-2510

[19] THE RESONANCE RAMAN-SPECTRUM OF PHENOXYL RADICAL [J].

TRIPATHI, GNR ;

SCHULER, RH .

JOURNAL OF CHEMICAL PHYSICS, 1984, 81 (01) :113-121

[20] ELECTRONIC-SPECTRA OF ISOLATED CATIONS IN SUPERSONIC JETS BY MASS-SELECTED ION-DIP SPECTROSCOPY - CATIONS OF BENZENE, P-DIFLUOROBENZENE, AND 1,3,5-TRIFLUOROBENZENE [J].

TSUCHIYA, Y ;

FUJII, M ;

ITO, M .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (12) :6965-6976