THE FREE-RADICAL CHEMISTRY OF ACYL TELLURIDES - MECHANISTIC STUDIES AND SYNTHETIC APPLICATIONS

被引:38
作者
CHEN, C [1 ]
CRICH, D [1 ]
机构
[1] UNIV ILLINOIS,DEPT CHEM,M-C 111,BOX 4348,CHICAGO,IL 60680
关键词
D O I
10.1016/0040-4039(93)85002-E
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Photolysis of acyl aryl tellurides in the presence of thiophenol results in the clean formation of aldehydes indicating homolytic cleavage of the acyl-Te bond and the involvement of acyl radicals. Further cyclization reactions of unsaturated acyltellurides are reported together with some chemistry of the cyclization products.
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页码:1545 / 1548
页数:4
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