SIMPLE AND EFFICIENCY METHOD FOR PREPARATION OF ORGANOTIN DIHYDRIDES

被引：6

作者：

DELEUZE, H

MAILLARD, B

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 490卷 / 1-2期

关键词：

BORANE; REDUCTION; DIALKYLSTANNANES; 1,3-DIOXA-2-STANNOLANES; SYNTHESIS;

D O I：

10.1016/0022-328X(94)05356-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new and efficient method of preparation of R(2)SnH(2) is proposed. Organodioxastannolanes were used as starting materials, these compounds being easily obtained by azeotropic distillation of water from a solution of diorganotin oxides and 1,2 diols in cyclohexane. Their reduction by commercial BH3/THF complex gave raw dialkyltin dihydrides with excellent yields and high purity degrees.

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页码：C14 / C17

页数：4

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