ANIONIC LIVING POLYMERIZATION OF AN ALPHA-METHYLSTYRENE DERIVATIVE CONTAINING THE BIS(DIETHYLAMINO)PHOSPHINO GROUP

被引：22

作者：

KASE, T ^{[1
]}

IMAHORI, M ^{[1
]}

KAZAMA, T ^{[1
]}

ISONO, Y ^{[1
]}

FUJIMOTO, T ^{[1
]}

机构：

[1] NAGAOKA UNIV TECHNOL,DEPT MAT SCI & TECHNOL,1603-1 KAMITOMIOKA,NAGAOKA,NIIGATA 94021,JAPAN

来源：

MACROMOLECULES | 1991年 / 24卷 / 08期

关键词：

D O I：

10.1021/ma00008a003

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The anionic polymerization of N,N,N',N'-tetraethyl-4-isopropenylphenylphosphonous diamide (PA) was studied. From the kinetic analyses, the thermodynamic parameters, DELTA-H(ss) and DELTA-H(ss), and the ceiling temperature, T(c), of the polymerization reaction of the PA monomer were found to be -6.5(1) kcal mol-1, -2.3(0) x 10 cal mol-1 K-1, and 283 K, respectively. It is concluded that if the polymerization of the monomer is initiated with n-butyllithium in tetrahydrofuran above its T(c) and then propagated below T(c), the polymerization proceeds at a first-order reaction rate without side reactions. The resulting poly(PA)s have predictable molecular weights and narrow molecular weight distributions.

引用

页码：1714 / 1719

页数：6

共 39 条

[31] SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF CYCLOPENTADIENYLIRON COMPLEXES WITH P-N-LIGANDS OF THE TYPE (C6H5)3P, (C6H5)2P(N(CH3)2), (C6H5)2P(N(C2H5)2), (C6H5)1P(N(CH3)2)2, (C6H5)1P(N(C2H5)2)2, P(N(CH3)2)3, P(N(C2H5)2)3 [J].

SCHUMANN, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 299 (02) :169-178

[32] ANIONIC-POLYMERIZATION OF TERTIARY AMINOSTYRENES AND CHARACTERIZATION OF THE POLYMERS [J].

SE, K ;

KIJIMA, M ;

FUJIMOTO, T .

POLYMER JOURNAL, 1988, 20 (09) :791-799

[33]

SHINDBAUER H, 1965, MONATSH CHEM, V96, P1936

[34]

SMITH B, 1953, J CHEM SOC, P861

[35] SYNTHESIS OF (R)-CYCLOHEXYLMETHYL-PARA-STYRYLPHOSPHINE AND THE PREPARATION OF POLYMER-BOUND OPTICALLY-ACTIVE PHOSPHINES [J].

SYBERT, PD ;

BERTELO, C ;

BIGELOW, WB ;

VARAPRATH, S ;

STILLE, JK .

MACROMOLECULES, 1981, 14 (03) :502-506

[36] ARTIFICIAL MEMBRANES FROM MULTIBLOCK COPOLYMER .4. 4-COMPONENT PENTABLOCK COPOLYMERS OF THE DSD'AD TYPE USABLE TO FABRICATE A CHARGE-MOSAIC MEMBRANE [J].

TAKAHASHI, S ;

MATSUMURA, K ;

TODA, M ;

FUJIMOTO, T ;

HASEGAWA, H ;

MIYAKI, Y .

POLYMER JOURNAL, 1986, 18 (01) :41-49

[37] TRANSPORT PROPERTIES OF CHARGE-MOSAIC MEMBRANES .1. THEORETICAL MODELS [J].

WEINSTEIN, JN ;

BUNOW, BJ ;

CAPLAN, SR .

DESALINATION, 1972, 11 (03) :341-377

[38] ANIONIC POLYMERIZATION OF ALPHA-METHYLSTYRENE [J].

WORSFOLD, DJ ;

BYWATER, S .

JOURNAL OF POLYMER SCIENCE, 1957, 26 (114) :299-304

[39] METALLORGANISCHE VERBINDUNGEN .23. UBER ALPHA-PHENYL-ISOPROPYL-KALIUM [J].

ZIEGLER, K ;

DISLICH, H .

CHEMISCHE BERICHTE-RECUEIL, 1957, 90 (06) :1107-1115

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