ADIABATIC OUTER SPHERE ELECTRON-TRANSFER THROUGH THE METAL ELECTROLYTE INTERFACE

被引：29

作者：

GORODYSKII, AV ^{[1
]}

KARASEVSKII, AI ^{[1
]}

MATYUSHOV, DV ^{[1
]}

机构：

[1] ACAD SCI UKSSR,INST GEN & INORGAN CHEM,32-34 PROSPECT PALLADINA,KIEV 252142,UKRAINE,USSR

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1991年 / 315卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(91)80058-X

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A theoretical study of the adiabatic reaction of electron transfer from a metal electrode to an acceptor level in a polar liquid is presented. The Gibbs energy of the electrochemical system along the electron transfer coordinate has been obtained at all values of the overlap of the metal and acceptor electronic states, over a wide range of the electrode overpotentials. The electron transfer probability has been calculated at high and low activation barriers of the reaction.

引用

页码：9 / 28

页数：20

共 33 条

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