COBALT-MEDIATED SYNTHESIS OF HIGHLY CROWDED STEROIDS - UNUSUAL OBSERVATIONS OF HINDERED ROTATION OF A TRIMETHYLSILYL GROUP

被引：24

作者：

BUTENSCHON, H ^{[1
]}

WINKLER, M ^{[1
]}

VOLLHARDT, KPC ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY LAWRENCE BERKELEY LAB,DIV MAT & MOLEC RES,BERKELEY,CA 94720

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1986年 / 05期

关键词：

D O I：

10.1039/c39860000388

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：388 / 390

页数：3

共 9 条

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[2] STRUCTURE OF (ETA-CYCLOPENTADIENYL)((3RSTAR,3ARSTAR)-5-5A-9A-9B-ETA-3-METHOXY-5-TRIMETHYLSILYL-2,3,3A,4,6,7,8,9-OCTAHYDRO-1H-BENZ[E]INDENE)COBALT,[CO(C5H5)(C17H28OSI)]
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[3] ALKYNE SCISSION ON A TRIMETALLIC FRAMEWORK - EXPERIMENTAL-EVIDENCE AND THEORETICAL-ANALYSIS
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[4] PRACTICAL, COBALT-MEDIATED, DIASTEREOSELECTIVE SYNTHESIS OF THE 11-(TRIMETHYLSILYL)-3-METHOXYESTRA-1,3,5(10),8(14),9(11)-PENTAENE NUCLEUS - A NOVEL STEROID INTERMEDIATE - 1ST OBSERVATION OF HINDERED ROTATION IN A VINYLTRIMETHYLSILANE
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (22) : 6710 - 6712
[5] HAIDUC I, 1977, ADV ORGANOMET CHEM, V15, P137
[6] MEAKIN P, 1971, J AM CHEM SOC, V93, P4701
[7] COBALT-MEDIATED TOTAL SYNTHESIS OF STEROIDS - THE A-]BCD APPROACH BY ENEDIYNE CYCLIZATION
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (09) : 1574 - 1583
[8] COBALT-MEDIATED [2+2+2]-CYCLOADDITIONS - A MATURING SYNTHETIC STRATEGY
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[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (08): : 539 - 556
[9] WENG CM, 1974, SYNTH COMMUN, P25

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