SYNTHESIS OF THIOLS VIA PALLADIUM-CATALYZED METHANOLYSIS OF THIOACETATES WITH BOROHYDRIDE EXCHANGE RESIN

被引：20

作者：

CHOI, J ^{[1
]}

YOON, NM ^{[1
]}

机构：

[1] SOGANG UNIV,DEPT CHEM,SEOUL 121742,SOUTH KOREA

来源：

SYNTHETIC COMMUNICATIONS | 1995年 / 25卷 / 17期

关键词：

D O I：

10.1080/00397919508011812

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various thiols are prepared quantitatively from the corresponding thioacetates via Pd catalyzed methanolysis with borohydride exchange resin under a mild and neutral conditions. One-pot synthesis of thiols from alkyl halides through the formation of alkyl thioacetates using thioacetate exchange resin followed by methanolysis is also described.

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页码：2655 / 2663

页数：9

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