ELECTROCHEMICAL OSCILLATORS - AN EXPERIMENTAL-STUDY OF THE INDIUM THIOCYANATE OSCILLATOR

被引：37

作者：

KOPER, MTM

SLUYTERS, JH

机构：

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1991年 / 303卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(91)85116-7

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The "classical" indium/thiocyanate oscillator is studied in some more detail at the HMDE. Several qualitative dependences are investigated. Multiperiodic "mixed-mode" oscillations and aperiodic oscillations are observed near the system's transition from steady state to oscillatory behaviour. These oscillations are very reminiscent of those observed in other (electro)chemical oscillators, and seem to indicate some kind of common mechanism.

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页码：65 / 72

页数：8

相关论文

共 20 条

[1] AN EXPERIMENTAL INVESTIGATION OF PERIODIC AND CHAOTIC ELECTROCHEMICAL OSCILLATIONS IN THE ANODIC-DISSOLUTION OF COPPER IN PHOSPHORIC-ACID [J].

ALBAHADILY, FN ;

SCHELL, M .

JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (07) :4312-4319

[2] MIXED-MODE OSCILLATIONS IN AN ELECTROCHEMICAL SYSTEM .1. A FAREY SEQUENCE WHICH DOES NOT OCCUR ON A TORUS [J].

ALBAHADILY, FN ;

RINGLAND, J ;

SCHELL, M .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (02) :813-821

[3] SHILNIKOV CHAOS DURING COPPER ELECTRODISSOLUTION [J].

BASSETT, MR ;

HUDSON, JL .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (24) :6963-6966

[4] ON ELECTROCHEMICAL OSCILLATOR [J].

DELEVIE, R .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1970, 25 (02) :257-+

[5] ON NEGATIVE FARADAIC ADMITTANCE IN REGION OF POLAROGRAPHIC MINIMUM OF IN(3) IN AQUEOUS NASCN SOLUTION [J].

DELEVIE, R ;

HUSOVSKY, AA .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1969, 22 (01) :29-&

[6] THE ANALYSIS OF CURRENT OSCILLATIONS ON THE BASIS OF THE RETARDATION OF ELECTRODE PROCESSES BY DIFFERENT SURFACTANTS [J].

DORFLER, HD ;

MULLER, E .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 135 (01) :37-53

[7]

FETNER N, 1990, J PHYS CHEM-US, V94, P6507

[8]

FRANCK UF, 1961, Z ELEKTROCHEM, V65, P156

[9] HOMOCLINIC ORBITS AND MIXED-MODE OSCILLATIONS IN FAR-FROM-EQUILIBRIUM SYSTEMS [J].

GASPARD, P ;

WANG, XJ .

JOURNAL OF STATISTICAL PHYSICS, 1987, 48 (1-2) :151-199

[10] BIFURCATION PHENOMENA NEAR HOMOCLINIC SYSTEMS - A 2-PARAMETER ANALYSIS [J].

GASPARD, P ;

KAPRAL, R ;

NICOLIS, G .

JOURNAL OF STATISTICAL PHYSICS, 1984, 35 (5-6) :697-727