DELTA-PYRONENE - SELECTIVE EPOXIDATION AND PREPARATION OF CYCLOCITRALS

被引：19

作者：

SERRAMEDAN, D

MARC, F

PEREYRE, M

FILLIATRE, C

CHABARDES, P

DELMOND, B

机构：

[1] UNIV BORDEAUX 1,CHIM ORGAN & ORGANOMET LAB,CNRS,351 COURS LIBERAT,F-33405 TALENCE,FRANCE

[2] UNIV BORDEAUX 1,INST PIN,F-33405 TALENCE,FRANCE

[3] RHONE POULENC RECH,CTR RECH CARRIERES,F-69192 ST FONS,FRANCE

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 31期

关键词：

D O I：

10.1016/S0040-4039(00)60109-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The selective obtention of epoxides from delta-pyronene has been realized using a peracid and a cyclodehydrohalogenation reaction. The isomerization of an epoxidic isomer with Lewis and protonic acids and on active alumina has been studied leading to cyclocitrals.

引用

页码：4457 / 4460

页数：4

共 24 条

[1] NEW GEOMETRIC ISOMERS OF VITAMIN-A AND CAROTENOIDS .11. 19,19,19-TRIFLUORORETINAL AND 20,20,20-TRIFLUORORETINAL
ASATO, AE
MEAD, D
DENNY, M
BOPP, TT
LIU, RSH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (18) : 4979 - 4981
[2] REARRANGEMENTS OF PINANE DERIVATIVES
BANTHORP.DV
[J]. QUARTERLY REVIEWS, 1966, 20 (03): : 373 - &
[3] CHABARDES P, 1990, Patent No. 9013249
[4] CHABARDES P, 1990, Patent No. 9013250
[5] GROUND-STATE SIGMATROPIC AND ELECTROCYCLIC REARRANGEMENTS IN SOME MONOTERPENES - PYROLYSIS OF ALPHA-PINENE
CROWLEY, KJ
TRAYNOR, SG
[J]. TETRAHEDRON, 1978, 34 (18) : 2783 - 2789
[6] DUCHESNE JP, 1991, Patent No. 446116
[7] DUCHESNE JP, 1990, Patent No. 902724
[8] A NEW REAGENT OF PRENYLATION - 1-LITHIO-2-METHYL-4-TRIMETHYLSILOXY-BUTADIENE
DUHAMEL, L
DUHAMEL, P
LECOUVE, JP
[J]. TETRAHEDRON, 1987, 43 (19) : 4339 - 4348
[9] OXIDATION OF ALLYL ALCOHOLS WITH LEAD(IV) ACETATE
EHRENFREUND, J
ZINK, MP
WOLF, HR
[J]. HELVETICA CHIMICA ACTA, 1974, 57 (04) : 1098 - 1116
[10] HOPF H, 1988, LIEBIGS ANN CHEM, P705

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