DELTA-PYRONENE - SELECTIVE EPOXIDATION AND PREPARATION OF CYCLOCITRALS

被引:19
作者
SERRAMEDAN, D
MARC, F
PEREYRE, M
FILLIATRE, C
CHABARDES, P
DELMOND, B
机构
[1] UNIV BORDEAUX 1,CHIM ORGAN & ORGANOMET LAB,CNRS,351 COURS LIBERAT,F-33405 TALENCE,FRANCE
[2] UNIV BORDEAUX 1,INST PIN,F-33405 TALENCE,FRANCE
[3] RHONE POULENC RECH,CTR RECH CARRIERES,F-69192 ST FONS,FRANCE
关键词
D O I
10.1016/S0040-4039(00)60109-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The selective obtention of epoxides from delta-pyronene has been realized using a peracid and a cyclodehydrohalogenation reaction. The isomerization of an epoxidic isomer with Lewis and protonic acids and on active alumina has been studied leading to cyclocitrals.
引用
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页码:4457 / 4460
页数:4
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