A STUDY OF THE PHOTOCHEMISTRY INDUCED ELECTRON-TRANSFER REACTIONS BETWEEN PYRIDINEDICARBONITRILES AND PRIMARY AND SECONDARY ALIPHATIC-AMINES

被引:7
作者
BERNARDI, R
CARONNA, T
POGGI, G
VITTIMBERGA, BM
机构
[1] DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY
[2] UNIV RHODE ISL,DEPT CHEM,KINGSTON,RI 02881
关键词
D O I
10.1002/jhet.5570310436
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A study on the photochemically induced electron-transfer from primary and secondary aliphatic amines as donors to pyridinedicarbonitriles as the acceptor is reported. A comparison between the substitution positions and the spin density distributions, obtained via theoretical calculations using the 6-31+G basis set, shows some discrepancies, and forms the basis of a hypothesis on the mechanism of the reaction.
引用
收藏
页码:903 / 908
页数:6
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