A STUDY OF THE PHOTOCHEMISTRY INDUCED ELECTRON-TRANSFER REACTIONS BETWEEN PYRIDINEDICARBONITRILES AND PRIMARY AND SECONDARY ALIPHATIC-AMINES

被引：7

作者：

BERNARDI, R

CARONNA, T

POGGI, G

VITTIMBERGA, BM

机构：

[1] DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

[2] UNIV RHODE ISL,DEPT CHEM,KINGSTON,RI 02881

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1994年 / 31卷 / 04期

关键词：

D O I：

10.1002/jhet.5570310436

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A study on the photochemically induced electron-transfer from primary and secondary aliphatic amines as donors to pyridinedicarbonitriles as the acceptor is reported. A comparison between the substitution positions and the spin density distributions, obtained via theoretical calculations using the 6-31+G basis set, shows some discrepancies, and forms the basis of a hypothesis on the mechanism of the reaction.

引用

页码：903 / 908

页数：6

共 14 条

[11] MOLECULAR ORBITAL STUDY OF NMR AND ELECTRONIC SPECTRA OF MONOCYANOPYRIDINES, DICYANOPYRIDINES, AND 2,4,6-TRICYANOPYRIDINE [J].