POLYDENTATE TERTIARY AMINE ALUMINUM-HYDRIDE ADDUCTS - MONOMERIC VERSUS POLYMERIC SPECIES

被引：46

作者：

ATWOOD, JL ^{[1
]}

BENNETT, FR ^{[1
]}

JONES, C ^{[1
]}

KOUTSANTONIS, GA ^{[1
]}

RASTON, CL ^{[1
]}

ROBINSON, KD ^{[1
]}

机构：

[1] GRIFFITH UNIV,DIV SCI & TECHNOL,NATHAN,QLD 4111,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 07期

关键词：

D O I：

10.1039/c39920000541

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of H3AlNMe3 with 1,3,5-trimethylhexahydro-1,3,5-triazine (tmtz) yields trigonal bipyramidal, monomeric [H3Al(tmtz)2], 1, or polymeric [H3Al(tmtz)] infinity, 2, which undergo N-CH2 cleavage at ca. 123-degrees-C; nitrogen-atoms in 1 and 2 are in apical positions, as also established for polymeric [H3Al(N,N,N',N'-tetramethylpropylenediamine)] infinity, in accordance with ab initio molecular orbital calculations on the model system H3Al(NH3)2.

引用

页码：541 / 543

页数：3

共 24 条

[1] THE ARCHETYPE FOR A NEW CLASS OF SIMPLE EXTENDED 3D HONEYCOMB FRAMEWORKS - THE SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF CD(CN)5/3(OH)1/3.1/3(C6H12N4), CD(CN)2.1/3(C6H12N4), AND CD(CN)2.2/3H2O.TBUOH (C6H12N4 = HEXAMETHYLENETETRAMINE) REVEALING 2 TOPOLOGICALLY EQUIVALENT BUT GEOMETRICALLY DIFFERENT FRAMEWORKS [J].

ABRAHAMS, BF ;

HOSKINS, BF ;

LIU, JP ;

ROBSON, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) :3045-3051

[2] MOLECULAR-STRUCTURE OF TRIMETHYLAMINE ALANE, H3ALN(CH3)3 [J].

ALMENNINGEN, A ;

GUNDERSEN, G ;

HAUGEN, T ;

HAALAND, A .

ACTA CHEMICA SCANDINAVICA, 1972, 26 (10) :3928-3934

[3]

ARCHER R, 1965, INORG CHEM, V4, P1358

[4] CATIONIC ALUMINUM HYDRIDES - [H2ALL]+[ALH4]-, L = N,N,N'N'',N''-PENTAMETHYLDIETHYLENETRIAMINE AND 1,4,8,11-TETRAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE [J].

ATWOOD, JL ;

ROBINSON, KD ;

JONES, C ;

RASTON, CL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (23) :1697-1699

[5] TERTIARY AMINE STABILIZED DIALANE [J].

ATWOOD, JL ;

BENNETT, FR ;

ELMS, FM ;

JONES, C ;

RASTON, CL ;

ROBINSON, KD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (21) :8183-8185

[6]

ATWOOD JL, UNPUB

[7] LASER-INDUCED CHEMICAL VAPOR-DEPOSITION OF ALUMINUM [J].

BAUM, TH ;

LARSON, CE ;

JACKSON, RL .

APPLIED PHYSICS LETTERS, 1989, 55 (12) :1264-1266

[8]

BENNETT FR, UNPUB

[9] A NEW STAGE IN THE DEVELOPMENT OF TRANSITION-METAL ALUMOHYDRIDES [J].

BULYCHEV, BM .

POLYHEDRON, 1990, 9 (2-3) :387-408

[10]

CARLEY DR, 1968, Patent No. 3375129

← 1 2 3 →