PHOTOEMISSION FROM GASEOUS AND CONDENSED MOLECULAR CARBORANE CLUSTER MOLECULES

被引：10

作者：

BYUN, D

LEE, S

HWANG, SD

HU, YF

BANCROFT, GM

GLASS, JA

ZHANG, JD

SPENCER, JT

MA, J

DOWBEN, PA

机构：

[1] UNIV NEBRASKA,DEPT PHYS,BEHLEN LAB PHYS,LINCOLN,NE 68588

[2] SYRACUSE UNIV,SOLID STATE SCI & TECHNOL PROGRAM,SYRACUSE,NY 13244

[3] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244

[4] SYRACUSE UNIV,KECK CTR MOLEC,SYRACUSE,NY 13244

[5] UNIV WESTERN ONTARIO,DEPT CHEM,LONDON N6A 5B7,ONTARIO,CANADA

[6] UNIV WISCONSIN,DEPT PHYS,MADISON,WI 53706

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1994年 / 69卷 / 02期

关键词：

CARBORANE; CLUSTER; CONDENSED PHASE; GAS; MNDO; PES;

D O I：

10.1016/0368-2048(94)02211-H

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The electronic structure of the nido-2,3-R2-2,3-dicarbahexaborane (R2C2B4H6) where R is C2H5) and closo-1,2-dicarbadodecaborane (C2B10H12) have been studied by photoemission spectroscopy (PES). Photoemission spectra for condensed nido-2,3-diethyl-2,3-dicarbahexaborane(8) ((C2H5)2C2B4H6) exhibited features in good agreement with molecular orbitals assigned by modified neglect of differential overlap (MNDO) semiempirical theoretical calculations. Similar agreement can be demonstrated for the closo-1,2-dicarbadodecaborane.

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页码：111 / 116

页数：6

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