THE ANGULAR TRIFLUOROMETHYL GROUP AT THE STEROIDAL-AB RING JUNCTION

被引：11

作者：

BLAZEJEWSKI, JC

LEGUYADER, F

WAKSELMAN, C

机构：

[1] CNRS-CERCOA, 94320 Thiais

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 04期

关键词：

ANGULAR TRIFLUOROMETHYL GROUP; 19,19,19-TRIFLUOROSTEROID; AROMATASE INHIBITOR; 9,9,9-TRIFLUORO WIELAND-MIESCHER KETONE; DIENOLATE ANION CYCLIZATION;

D O I：

10.1016/S0040-4039(00)93979-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of a 19,19,19-trifluorosteroid is described starting from the 9,9,9-trifluoro analogue of the Wieland-Miescher ketone via a dienolate anion cyclisation as the key step.

引用

页码：499 / 502

页数：4

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