PREPARATIONS OF ANGULARLY TRIFLUOROMETHYLATED COMPOUNDS

被引：15

作者：

HANZAWA, Y

ITO, H

KOHARA, N

SASAKI, H

FUKUDA, H

MORIKAWA, T

TAGUCHI, T

IITAKA, Y

机构：

[1] TOKYO COLL PHARM,1432-1 HORINOUCHI,HACHIOJI,TOKYO 19203,JAPAN

[2] TEIKYO UNIV,FAC MED,HACHIOJI,TOKYO 19203,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 33期

关键词：

ANGULAR TRIFLUOROMETHYL GROUP; 19,19,19-TRIFLUOROSTEROID; AROMATASE INHIBITOR; RADICAL CYCLIZATION; INTRAMOLECULAR MICHAEL ADDITION;

D O I：

10.1016/S0040-4039(00)79887-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Angularly trifluoromethylated cis-bicyclic compounds were effectively produced by intramolecular radical and Michael addition reactions. As a typical target molecule, 19,19,19-trifluorosteroid was prepared using an angularly trifluoromethylated bicyclic compound.

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页码：4143 / 4146

页数：4

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