EFFECT OF COPOLYMER COMPOSITION AND CONVERSION ON THE GLASS-TRANSITION OF METHYL ACRYLATE-METHYL METHACRYLATE COPOLYMERS

被引：27

作者：

FERNANDEZGARCIA, M ^{[1
]}

LOPEZGONZALEZ, MMC ^{[1
]}

BARRALESRIENDA, JM ^{[1
]}

MADRUGA, EL ^{[1
]}

ARIAS, C ^{[1
]}

机构：

[1] UNIV COMPLUTENSE MADRID,FAC FARM,DEPT QUIM FIS FARMACEUT,E-28040 MADRID,SPAIN

来源：

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS | 1994年 / 32卷 / 07期

关键词：

METHYL METHACRYLATE-METHYL ACRYLATE COPOLYMERS; FREE RADICAL COPOLYMERIZATION; LOW AND HIGH CONVERSION; GLASS TRANSITION TEMPERATURE; SEQUENCE DISTRIBUTION; COMPOSITIONAL VARIATION OF GLASS TRANSITION; MODELING;

D O I：

10.1002/polb.1994.090320707

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The glass transition of methyl methacrylate-methyl acrylate copolymers over a wide range of conversion and sequence distribution have been analyzed with the only purpose of predicting the change in the glass transition in copolymers as a function of conversion. and consequently of comonomer sequence distribution. (C) 1994 John Wiley & Sons, Inc.

引用

页码：1191 / 1203

页数：13

共 38 条

[11]

Fox TG, 1956, B AM PHYS SOC, V1, P123

[12] IDEAL COPOLYMERS AND THE 2ND-ORDER TRANSITIONS OF SYNTHETIC RUBBERS .1. NON-CRYSTALLINE COPOLYMERS [J].

GORDON, M ;

TAYLOR, JS .

JOURNAL OF APPLIED CHEMISTRY, 1952, 2 (09) :493-500

[13] MODELING AND SIMULATION OF EMULSION COPOLYMERIZATION OF MONOMERS OF DIFFERENT POLARITIES - RELATIONSHIP POLYMERIZATION PROCESS-MICROSTRUCTURE-PROPERTIES [J].

GUILLOT, J .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1990, 35-6 :269-289

[14]

GUILLOT J, 1991, MAKROMOL CHEM-RAPID, V12, P117

[15]

GUILLOT J, 1983, 16EME C AFTPV CANN, P179

[16] ROLE OF TRIAD CONCENTRATION IN GLASS-TRANSITION TEMPERATURES OF COPOLYMERS [J].

HAM, GE .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1975, A 9 (03) :461-467

[17]

HARWOOD HJ, 1970, J POLYM SCI C, V30, P573

[18] ALTERNATING COPOLYMERIZATION THROUGH COMPLEXES OF CONJUGATED VINYL MONOMERS-ALKYLALUMINUM HALIDES [J].

HIROOKA, M ;

YABUUCHI, H ;

ISEKI, J ;

NAKAI, Y .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1968, 6 (5PA1) :1381-&

[19] GLASS-TRANSITION TEMPERATURE AND SEQUENTIAL STRUCTURE OF EQUIMOLAR COPOLYMERS [J].

HIROOKA, M ;

KATO, T .

JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1974, 12 (01) :31-37

[20]

ILLERS KH, 1966, BERICH BUNSEN GESELL, V70, P353

← 1 2 3 4 →