THE OXOVANADIUM-ORGANOARSONATE SYSTEM - [2CH3OH-SUBSET-OF-V12O14(OH)(4)(PHASO(3))(10)](4-) AND [2H2O-SUBSET-OF-V12O12(OH)(2)(H2O)(2)(PHASO(3))(10)(PHASO(3)H)(4)](2-), CLUSTERS WITH NANOMETER DIMENSIONS AND CAVITIES FOR NEUTRAL MOLECULES

被引:65
作者
KHAN, MI [1 ]
ZUBIETA, J [1 ]
机构
[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 07期
关键词
D O I
10.1002/anie.199407601
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Neutral molecules are encapsulated in the cluster anions in the title, which were produced by solvothermal reactions of [nBu4N]3[H3V10O28] and PhAsO3H2 in CH3OH/H2O (99:1) with and without Et4NCl. The structures are shown schematically below. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码:760 / 762
页数:3
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