A NOVEL BINUCLEAR RUTHENIUM(III) COMPOUND TRIPLY BRIDGED BY CHLORIDE AND DISULFIDE LIGANDS, [RUCL(P(OME)3)2(MU-CL)2(MU-S2)RUCL(P(OME)3)2]

被引：26

作者：

MATSUMOTO, T ^{[1
]}

MATSUMOTO, K ^{[1
]}

机构：

[1] WASEDA UNIV, DEPT CHEM, SHINJUKU KU, TOKYO 169, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 04期

关键词：

D O I：

10.1246/cl.1992.559

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A diruthenium compound with a novel Ru2(S2)Cl2 core has been synthesized. The X-ray crystal study shows that the disulfide ligand bridges the ruthenium atoms in a cis manner with the S-S distance of 1.971 (4) angstrom. The compound has a redox potential of -0.57 V (vs. Ag+/Ag) and a characteristic absorption band at 737 nm.

引用

页码：559 / 562

页数：4

共 9 条

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