SIMULTANEOUS COORDINATION OF THE ENDO-CONFORMATIONS AND EXO-CONFORMATIONS OF A CROWN THIOETHER LIGAND TO A SINGLE METAL CENTER - SYNTHESIS AND STRUCTURE OF [AG(L1)2][CF3SO3], WHERE L1 = 2,5,8-TRITHIA[9]ORTHO-BENZENOPHANE

被引：31

作者：

DEGROOT, B ^{[1
]}

LOEB, SJ ^{[1
]}

机构：

[1] UNIV WINDSOR,DEPT CHEM,WINDSOR N9B 3P4,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1990年 / 24期

关键词：

D O I：

10.1039/c39900001755

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Ag(L1)2][CF3SO3] is the first example of a complex which contains both the free ligand exo- and the fully organized endo-conformations of a crown thioether ligand; 1H NMR spectroscopy shows evidence for the facile metalpromoted interconversion of these conformations.

引用

页码：1755 / 1757

页数：3

共 21 条

[1] HOMOLEPTIC HEXATHIA COMPLEXES OF RHODIUM - THE SYNTHESIS, ELECTROCHEMISTRY, AND SINGLE-CRYSTAL X-RAY STRUCTURE OF [RH1,4,7-TRITHIACYCLONONANE2][PF6]3
BLAKE, AJ
GOULD, RO
HOLDER, AJ
HYDE, TI
SCHRODER, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (07): : 1861 - 1865
[2] PI-EFFECTS IN THIOETHER MACROCYCLIC COMPLEXES - THE STABILIZATION AND STRUCTURE OF THE LOW-SPIN FE-3 THIOETHER COMPLEX [FE([9]ANES3)2]3+
BLAKE, AJ
HOLDER, AJ
HYDE, TI
SCHRODER, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (19) : 1433 - 1434
[3] GOLD THIOETHER CHEMISTRY - SYNTHESIS, STRUCTURE, AND REDOX INTERCONVERSION OF [AU(1,4,7-TRITHIACYCLONONANE)2]+/2+/3+
BLAKE, AJ
GOULD, RO
GREIG, JA
HOLDER, AJ
HYDE, TI
SCHRODER, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (13) : 876 - 878
[4] C-H ACTIVATION OF COORDINATED CROWNS THIOETHERS - DEPROTONATION AND RING-OPENING OF [M([9]ANES3)2]3+ (M = CO, RH, IR) - CRYSTAL-STRUCTURE OF [RH(H2C=CHS(CH2)2S(CH2)2S)([9]ANES3)](PF6)2 ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE)
BLAKE, AJ
HOLDER, AJ
HYDE, TI
KUPPERS, HJ
SCHRODER, M
STOTZEL, S
WIEGHARDT, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (21) : 1600 - 1602
[5] BIS(1,4,7-TRITHIACYCLONONANE)GOLD DICATION - A PARAMAGNETIC, MONONUCLEAR AU-II COMPLEX
BLAKE, AJ
GREIG, JA
HOLDER, AJ
HYDE, TI
TAYLOR, A
SCHRODER, M
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (02): : 197 - 198
[6] CROWN THIOETHER CHEMISTRY - THE SILVER(I) COMPLEXES OF TRITHIA-9-CROWN-3, TRITHIA-12-CROWN-3, AND HEXATHIA-18-CROWN-6
BLOWER, PJ
CLARKSON, JA
RAWLE, SC
HARTMAN, JR
WOLF, RE
YAGBASAN, R
BOTT, SG
COOPER, SR
[J]. INORGANIC CHEMISTRY, 1989, 28 (21) : 4040 - 4046
[7] A NEW CONFORMATION AND COORDINATION MODE FOR 1,4,7-TRITHIACYCLONONANE (9S3) - STRUCTURE OF [CU2(9S3)3](BF4)2.H2O
CLARKSON, JA
YAGBASAN, R
BLOWER, PJ
COOPER, SR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (17) : 1244 - 1245
[8] CROWN THIOETHER CHEMISTRY
COOPER, SR
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (04) : 141 - 146
[9] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE CROWN THIOETHER 1,3,6,9,11,14-HEXATHIACYCLOHEXADECANE (16S6) AND THE COPPER(I) COMPLEX [CU(16S6)][CLO4]
DEGROOT, B
LOEB, SJ
[J]. INORGANIC CHEMISTRY, 1989, 28 (18) : 3573 - 3578
[10] CROWN THIOETHER LIGANDS CONTAINING RIGID XYLYL UNITS - SYNTHESIS AND STRUCTURES OF 2,5,8-TRITHIA[9]-O-BENZENOPHANE (TTOB), 2,5,8-TRITHIA[9]-M-BENZENOPHANE (TTMB), AND FAC-MO(CO)3(TTOB).DMSO
DEGROOT, B
LOEB, SJ
[J]. INORGANIC CHEMISTRY, 1990, 29 (20) : 4084 - 4090

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