SIMULTANEOUS COORDINATION OF THE ENDO-CONFORMATIONS AND EXO-CONFORMATIONS OF A CROWN THIOETHER LIGAND TO A SINGLE METAL CENTER - SYNTHESIS AND STRUCTURE OF [AG(L1)2][CF3SO3], WHERE L1 = 2,5,8-TRITHIA[9]ORTHO-BENZENOPHANE

被引：31

作者：

DEGROOT, B ^{[1
]}

LOEB, SJ ^{[1
]}

机构：

[1] UNIV WINDSOR,DEPT CHEM,WINDSOR N9B 3P4,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1990年 / 24期

关键词：

D O I：

10.1039/c39900001755

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Ag(L1)2][CF3SO3] is the first example of a complex which contains both the free ligand exo- and the fully organized endo-conformations of a crown thioether ligand; 1H NMR spectroscopy shows evidence for the facile metalpromoted interconversion of these conformations.

引用

页码：1755 / 1757

页数：3

共 21 条

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