SELECTIVE MONOFUNCTIONALIZATION OF POLYAZA[N]PARACYCLOPHANES

被引：9

作者：

BURGUETE, MI

ESCUDER, B

LUIS, SV

MIRAVET, JF

GARCIAESPANA, E

机构：

[1] UNIV JAUME 1,DEPT EXPTL SCI,ORGAN CHEM LAB,E-12080 CASTELLO DE PLANA,SPAIN

[2] UNIV VALENCIA,DEPT INORGAN CHEM,E-46100 BURJASSOT,SPAIN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 48期

关键词：

D O I：

10.1016/0040-4039(94)88432-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new strategy to the preparation of selectively functionalized polyazamacrocycles is presented. Polyaza[n]paracyclophanes receptors are able to efficiently direct their own selective monofunctionalization upon interaction with simple guests such as metal cations. This enables the preparation of novel receptors functionalized at one of the benzylic nitrogen atoms with a variety of groups.

引用

收藏

页码：9075 / 9078

页数：4

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