SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF (ET4N)2[MN10O2CL8((OCH2)3CME)6].4MEOH.2H2O, A MNII,III MIXED-VALENCE CLUSTER WITH THE DECAMETALLATE CORE GEOMETRY

被引：46

作者：

CAVALUZZO, M ^{[1
]}

CHEN, Q ^{[1
]}

ZUBIETA, J ^{[1
]}

机构：

[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 02期

关键词：

D O I：

10.1039/c39930000131

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of (Et4N)2MnCl4 with MeC(CH2OH)3 in acetonitrile in the presence of atmospheric oxygen yields the oxoalkoxomanganese cluster (Et4N)2[Mn10O2Cl8{(OCH2)3CMe}6].4MeOH.2H2O, a Mn(II,III) mixed valence species exhibiting the decametallate core geometry, {M10O2L26}.

引用

收藏

页码：131 / 133

页数：3

相关论文

共 14 条

[1] METAL ALKOXIDES AS PRECURSORS FOR ELECTRONIC AND CERAMIC MATERIALS [J].

BRADLEY, DC .

CHEMICAL REVIEWS, 1989, 89 (06) :1317-1322

[2]

Brown I. D., 1981, STRUCTURE BONDING CR, VII, P1

[3] SYNTHESIS, STRUCTURAL PRINCIPLES, AND REACTIVITY OF HETEROMETALLIC ALKOXIDES [J].

CAULTON, KG ;

HUBERTPFALZGRAF, LG .

CHEMICAL REVIEWS, 1990, 90 (06) :969-995

[4] COORDINATION CHEMISTRY OF SOLUBLE METAL-OXIDES OF MOLYBDENUM AND VANADIUM [J].

CHEN, Q ;

ZUBIETA, J .

COORDINATION CHEMISTRY REVIEWS, 1992, 114 (02) :107-167

[5] COORDINATION-COMPOUNDS OF POLYOXOVANADATES WITH A HEXAMETALATE CORE - CHEMICAL AND STRUCTURAL CHARACTERIZATION OF [V(V)6O13((OCH2)3CR(2]2-, [V(V)6O11(OH)2((OCH2)3CR(2], [V(IV)4V(V)2O9(OH)4((OCH2)3CR(2]2-, AND [V(IV)6O7(OH)6((OCH2)3CR(2]2- [J].

CHEN, Q ;

GOSHORN, DP ;

SCHOLES, CP ;

TAN, XL ;

ZUBIETA, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (12) :4667-4681

[6] REACTIONS OF METAL METAL MULTIPLE BONDS .10. REACTIONS OF MO2(OR)6 (M=M) AND [MO(OR)4]X COMPOUNDS WITH MOLECULAR-OXYGEN - PREPARATION AND CHARACTERIZATION OF OXO ALKOXIDES OF MOLYBDENUM - MOO2(OR)2, MOO2(OR)2(BPY), MOO(OR)4, MO3O(OR)10,MO4O8(OR)4(PY)4, AND MO6O10(OR)12 [J].

CHISHOLM, MH ;

FOLTING, K ;

HUFFMAN, JC ;

KIRKPATRICK, CC .

INORGANIC CHEMISTRY, 1984, 23 (08) :1021-1037

[7] SOLUTION STRUCTURE ELUCIDATION OF EARLY-TRANSITION-METAL POLYOXOALKOXIDES USING O-17 NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY [J].

DAY, VW ;

EBERSPACHER, TA ;

KLEMPERER, WG ;

PARK, CW ;

ROSENBERG, FS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (21) :8190-8192

[8] [MN10O14(N(CH2CH2NH2)3)6]8+ - A MIXED-VALENCE POLYOXOMANGANESE POLYCATION POSSESSING STRUCTURAL SIMILARITIES TO NATURALLY-OCCURRING LAYERED MANGANESE OXIDES [J].

HAGEN, KS ;

ARMSTRONG, WH ;

OLMSTEAD, MM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (02) :774-775

[9] SYNTHESIS AND STRUCTURE OF A NOVEL HEXANUCLEAR IRON(III) COMPLEX CONTAINING 6 TERMINAL AND 12 BRIDGING ALKOXO GROUPS AND ONE MU-6-OXO BRIDGE [J].

HEGETSCHWEILER, K ;

SCHMALLE, H ;

STREIT, HM ;

SCHNEIDER, W .

INORGANIC CHEMISTRY, 1990, 29 (18) :3625-3627

[10]

HUBERTPFALZGRAF LG, 1987, NEW J CHEM, V11, P665