ALCL3-N,N-DIMETHYLANILINE - A NOVEL BENZYL AND ALLYL ETHER CLEAVAGE REAGENT

被引：34

作者：

AKIYAMA, T

HIROFUJI, H

OZAKI, S

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 07期

关键词：

D O I：

10.1246/bcsj.65.1932

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A combination system of AlCl3-N,N-dimethylaniline was found to cleave benzyl ethers readily to give parent alcohols in excellent yields. The system also cleaved allyl as well as methyl ethers. Numerous functional groups such as benzoyloxy, phenylthio, and olefinic double bond were not affected. Comparisons of AlCl3-N,N-dimethylaniline and AlCl3-anisole were described.

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页码：1932 / 1938

页数：7

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