OXIDATION OF DIAZO-COMPOUNDS BY DIMETHYL DIOXIRANE - AN EXTREMELY MILD AND EFFICIENT METHOD FOR THE PREPARATION OF LABILE ALPHA-OXO-ALDEHYDES

被引：38

作者：

IHMELS, H ^{[1
]}

MAGGINI, M ^{[1
]}

PRATO, M ^{[1
]}

SCORRANO, G ^{[1
]}

机构：

[1] CTR CNR MECCANISMI REAZ ORGAN,DIPARTIMENTO CHIM ORGAN,VIA MARZOLO 1,I-35131 PADUA,ITALY

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 43期

关键词：

D O I：

10.1016/0040-4039(91)80792-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel method for the preparation of alpha-oxo-aldehydes by dimethyl dioxirane oxidation of alpha-diazoketones is described. The procedure is particularly useful when the desired compound cannot be purified by chromatography or distillation: the by-products (acetone and nitrogen) can be evaporated and the reaction crude consists only of the pure compound.

引用

页码：6215 / 6218

页数：4

共 40 条

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