CONFORMATIONALLY BIASED TRI-BASIC AND DI-BASIC 1,3,5-TRIAZACYCLOHEXYL LIGANDS

被引：15

作者：

DEANGELIS, S

BATSANOV, A

NORMAN, TJ

PARKER, D

SENANAYAKE, K

VEPSALAINEN, J

机构：

[1] UNIV DURHAM,DEPT CHEM,DURHAM DH1 3LE,ENGLAND

[2] UNIV KUOPIO,DEPT CHEM,SF-70211 KUOPIO,FINLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 22期

关键词：

D O I：

10.1039/c39950002361

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The biased ligand cis-cis-2,4,6-trimethyl-1,3,5-triaminocyclohexane is weakly basic and may be converted into di- and tri-basic complexing agents bearing hydyoxyphenyl, carboxylate or phosphinate groups; an unusual tricyclic bis-aminal intermediate hydrolyses in acidic media to yield a stable bicyclic amidine via an intramolecular hydride transfer mechanism.

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页码：2361 / 2363

页数：3

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