DIFFUSE ABSENCES DUE TO THE ATOMIC SIZE EFFECT

被引:36
作者
BUTLER, BD
WITHERS, RL
WELBERRY, TR
机构
来源
ACTA CRYSTALLOGRAPHICA SECTION A | 1992年 / 48卷
关键词
D O I
10.1107/S0108767392003131
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Diffuse intensity absences, on reciprocal planes that pass through the Bragg positions, have been observed in diffraction patterns of Zr0.61Y0.39O1.81 and (Ta2O5).7%(WO3). These absences, occurring on planes normal to near-neighbour directions and high-lighted by sheets of diffuse intensity on either side, are shown to result naturally from atomic size effect distortions. The origins of these diffuse features are explained, using both real-space and modulation-wave approaches, by concentrating on a Monte Carlo simulated two-dimensional binary alloy. These absences, which should be characteristic of systems that distort via the size effect, result from intensity components that do not depend on scattering-factor differences and so will be most prominent when the atomic species have similar scattering powers, thus suppressing the normal size effect intensity component [Warren, Averbach & Roberts (1951). J. Appl. Phys. 22, 1493-1496].
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页码:737 / 746
页数:10
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