THERMODYNAMIC MODELING AND EXPERIMENTAL INVESTIGATIONS OF THE CSCL-CACL2-PUCL3 SYSTEM

被引：4

作者：

FOLTYN, EM ^{[1
]}

MULFORD, RNR ^{[1
]}

AXLER, KM ^{[1
]}

ESPINOZA, JM ^{[1
]}

MURRAY, AM ^{[1
]}

机构：

[1] ROCKWELL INT CORP,DIV ROCKY FLATS,GOLDEN,CO 80401

来源：

JOURNAL OF NUCLEAR MATERIALS | 1991年 / 178卷 / 01期

关键词：

12;

D O I：

10.1016/0022-3115(91)90459-K

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The CsCl-CaCl2-PuCl3 ternary diagram was calculated from the known binary diagrams. The various principle features, ternary eutectics and peritectics, were verified experimentally by differential thermal analysis. Also, the phase boundaries lying in the polythermal section between a PuCl3 mole fraction of 0.4 on the CsCl-PuCl3 binary and CaCl2 were determined experimentally in some detail. Because the measurements agree well with the prediction, it is assumed that the calculation together with the experimental verification of some of the points has established the entire ternary phase diagram. In addition, d-spacing data from the X-ray diffraction pattern of the compound CsPu2Cl7 are reported.

引用

页码：93 / 98

页数：6