ALKYLATION OF CHIRAL, PHOSPHORUS-STABILIZED CARBANIONS - SUBSTITUENT EFFECTS ON THE ALKYLATION SELECTIVITY

被引:48
作者
DENMARK, SE
CHEN, CT
机构
[1] Roger Adams Laboratory, Department of Chemistry, University of Illinois, Urbana
关键词
D O I
10.1021/jo00090a004
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The alkylation of a series of enantiomerically pure cis and trans 3-substituted 2-benzyl-6-methyl-1,3,2-oxazaphosphorinane 2-oxides was found to be sensitive to the bulk of the N-substituents.
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页码:2922 / 2924
页数:3
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