SILANE NITRILE - MATRIX-ISOLATION, ADDUCT WITH HYDROGEN

被引：61

作者：

MAIER, G

GLATTHAAR, J

机构：

[1] Institut für Organische Chemie, Universität Giessen, D-35392

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 04期

关键词：

D O I：

10.1002/anie.199404731

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

How do carbon and silicon chemistry differ? For example, the cyanide⇌isocyanide equilibrium is completely reversed in the sila series. According to calculations silane nitrile (2) is higher in energy than its isomer 1, which has been known for much longer. The matrix isolation of 2 has now been achieved; 2 is the first silicon compound of the nitrile type. (Formula Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：473 / 475

页数：3

共 31 条

[11]

GASPAR PP, 1978, REACTIVE INTERMEDIAT, V1, P229

[12]

GASPAR PP, 1981, REACTIVE INTERMEDIAT, V2, P335

[13] GENERATION AND IDENTIFICATION OF NEUTRAL AND CATIONIC HYDROGENSILAISOCYANID (IMINOSILICON, HNSI) BY NEUTRALIZATION-REIONIZATION MASS-SPECTROMETRY AND GAUSSIAN-1 AB-INITIO MOLECULAR-ORBITAL CALCULATIONS [J].