THE ELECTROCHEMISTRY OF THE LI/SOCL2 CELL .1. THE PASSIVATION OF THE CATHODE

被引:13
作者
HAGAN, WP [1 ]
HAMPSON, NA [1 ]
PACKER, RK [1 ]
机构
[1] ADMIRALTY RES ESTAB,PORTLAND DT5 2JS,DORSET,ENGLAND
关键词
ANODES - Lithium - CATHODES - Carbon Black - ELECTROCHEMISTRY - ELECTRODES - Carbon;
D O I
10.1016/0013-4686(86)87038-4
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The ambient temperature cathodic electroreduction characteristics of cathode limited Li-SOCl//2 cells have been investigated at discharge rates up to 170 ma cm** minus **2 and over a possible working concentration range. The effect of varying cathode thickness on both the passivation times and polarization curves are discussed. The effect of discontinuous passivations on the overall passivation time have been investigated and are discussed in relation to the nature and mobility of the passivating layer.
引用
收藏
页码:699 / 704
页数:6
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SCHLAIKJER CR, 1983, LITHIUM BATTERIES
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SZPAK S, 1983, POWER SOURCES, V9, P403