EXCESS-ENTHALPIES OF ((ETHANOL OR PROPAN-1-OL OR METHYL 1,1-DIMETHYLETHYL ETHER) PLUS (2,3-DIMETHYLBUTANE OR 2,2,4-TRIMETHYLPENTANE))

被引：26

作者：

WANG, L

BENSON, GC

LU, BCY

机构：

[1] Department of Chemical Engineering, University of Ottawa, Ottawa, Ont. K1N 9B4

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 1992年 / 24卷 / 12期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0021-9614(05)80271-X

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Excess molar enthalpies, measured at T = 298.15 K in a flow microcalorimeter, are reported for the six binary mixtures containing ethanol or propan-1-ol or methyl 1,1-dimethylethyl ether, together with 2,3-dimethylbutane or 2,2,4-trimethylpentane. Smooth representations of the results are presented, and an analysis in terms of an association model with a Flory contribution term is described. © 1992 Academic Press Limited All rights reserved.

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页码：1305 / 1310

页数：6

相关论文

共 12 条

[1] THERMODYNAMIC PROPERTIES OF MIXTURES OF SMALL NONPOLAR MOLECULES [J].

ABE, A ;

FLORY, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (09) :1838-&

[2] VAPOR-LIQUID-EQUILIBRIUM OF THE SYSTEMS 1-PROPANOL-2,2,4-TRIMETHYLPENTANE AND 2-PROPANOL-NORMAL-HEXANE [J].

BERRO, C ;

NEAU, E ;

ROGALSKI, M .

FLUID PHASE EQUILIBRIA, 1981, 7 (01) :41-54

[3]

BROWN I, 1955, AUST J CHEM, V8, P361

[4] STATISTICAL THERMODYNAMICS OF LIQUID MIXTURES [J].

FLORY, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (09) :1833-+

[5] EXCESS-ENTHALPIES OF BINARY-MIXTURES OF NORMAL-HEPTANE WITH HEXANE ISOMERS [J].

KIMURA, F ;

BENSON, GC ;

HALPIN, CJ .

FLUID PHASE EQUILIBRIA, 1983, 11 (03) :245-250

[6] DENSITIES AND LIQUID-VAPOR EQUILIBRIA OF THE SYSTEM ETHANOL-ISOOCTANE (2,2,4-TRIMETHYLPENTANE) BETWEEN 0-DEGREES AND 50-DEGREES [J].

KRETSCHMER, CB ;

NOWAKOWSKA, J ;

WIEBE, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1948, 70 (05) :1785-1790

[7] APPLICATION OF A FLOW MICROCALORIMETER TO DETERMINE EXCESS ENTHALPIES OF BINARY-MIXTURES OF NONELECTROLYTES [J].

TANAKA, R ;

DARCY, PJ ;

BENSON, GC .

THERMOCHIMICA ACTA, 1975, 11 (02) :163-175

[8] PREDICTION OF EXCESS VOLUMES OF 1-ALKANOL + BRANCHED ALIPHATIC HYDROCARBON BINARY-SYSTEMS IN TERMS OF AN ASSOCIATION MODEL WITH A FLORY CONTRIBUTION TERM [J].

TRESZCZANOWICZ, AJ ;

BENSON, GC .

FLUID PHASE EQUILIBRIA, 1988, 41 (1-2) :31-42

[9] EXCESS VOLUMES OF ALKANOL + ALKANE BINARY-SYSTEMS IN TERMS OF AN ASSOCIATION MODEL WITH A FLORY CONTRIBUTION TERM [J].

TRESZCZANOWICZ, AJ ;

BENSON, GC .

FLUID PHASE EQUILIBRIA, 1985, 23 (2-3) :117-135

[10] EXCESS-ENTHALPIES OF (ETHANOL PLUS HEXANE PLUS DECANE OR DODECANE) AT THE TEMPERATURE 298.15-K [J].

WANG, L ;

BENSON, GC ;

LU, BCY .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1992, 24 (11) :1135-1143