USE OF CIS-3-CYCLOBUTENE-1,2-DIMETHANOL IN STEREOSELECTIVE ROUTES TO SOME NATURALLY-OCCURRING CONJUGATED DIENES AND TRIENES

被引：11

作者：

HODGETTS, KJ

SAENGCHANTARA, ST

WALLIS, CJ

WALLACE, TW

机构：

[1] UNIV SALFORD,DEPT CHEM & APPL CHEM,SALFORD M5 4WT,LANCS,ENGLAND

[2] GLAXO GRP RES LTD,WARE SG12 0DP,HERTS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 39期

关键词：

D O I：

10.1016/S0040-4039(00)73742-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thermal electrocyclic ring-opening of 4-alkyl-2-cyclobutene-1-carbaldehydes occurs at low temperature to give (2Z,4E)-alka-2,4-dienals exclusively, and this process is exploited en route to various isomeric naturally occurring 1,3,5-alkatrienes and 2,4-decadienoates from a single precursor, cis-3-cyclobutene-1,2-dimethanol 4.

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页码：6321 / 6324

页数：4

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