ION-PAIRING IN [BIS(TRIMETHYLSILYL)AMIDO]POTASSIUM - X-RAY CRYSTAL-STRUCTURE OF UNSOLVATED [KN(SIME3)2]2

被引:92
作者
TESH, KF
HANUSA, TP
HUFFMAN, JC
机构
[1] VANDERBILT UNIV,DEPT CHEM,NASHVILLE,TN 37240
[2] INDIANA UNIV,CTR MOLEC SCI,DEPT CHEM,BLOOMINGTON,IN 47401
关键词
D O I
10.1021/ic00333a029
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The use of sterically bulky ligands to enforce low coordination numbers in metal complexes is well established.1A variety of [bis(trimethylsilyl)amido]metal complexes are known in which the metal center is two- and three-coordinate, and the electronic, spectroscopic, and structural properties of these species have been extensively studied.2-15. © 1990, American Chemical Society. All rights reserved.
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页码:1584 / 1586
页数:3
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